七時に起きます。

When an action happens at a certain time, that time can be stated with a time argument. Time arguments come in two main forms:

Numerical time arguments

The time stated as we have just learned in this lesson can be turned into a time argument by adding the particle に

七時に起きます。
I get up at seven.

Non-numerical time arguments

Non-numerical time expressions can be used as arguments without any particle.

あした勉強します。
I’m going to study tomorrow.

However, with days of the week, the use of に is optional.

月曜日[に]行きます。
I’m going on Monday.

Numerical and non-numerical arguments can be combined.

きのう六時に起きました。
Yesterday I got up at six.